To break it down into the simplest terms, photovoltaic cells are a part of solar panels. Solar panels have a lot of photovoltaic cells lined upon them to convert sunlight into voltage. The solar panels use the voltage generated by the photovoltaic cells and convert it into power. Of course, this. Photovoltaic cells generate voltage by having a difference in electrons on their back and front. The front has a higher number of electrons,. Solar panels are the part of the solar array that gathers electricity and converts it into electricity. Solar panels are lined with photovoltaic cells. There is the photovoltaic solar array, which I discussed above. They consist of photovoltaic cells and solar panels and convert sunlight directly into electricity. They all come in a. Thus far, we've been talking about photovoltaic solar power or converting sunlight directly into electricity. But solar power is more than just photovoltaic. Solar power is about converting sunlight into usable energy, including heat. So thermal solar power uses.